how long and what topics could cover an interview with the COO of a company?

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How long. Probably an hour, anyone with "chief" in their title will really know the business and have a lot to say. Regarding topics I would have a list of at least 5 questions for them mainly nontechnical like how do they feel about devs talking directly to users? What would he do if a deadline where approaching and the Dev team said they were not ready? How do they deal with scope creep? What roles to project managers play? Why would a Dev want to work there? Do they do user testing with actual users. How does he see the apps you will be working with benefiting the company. What are the goals for next year?